肉眼
化学
壳聚糖
水溶液
检出限
硫醇
胺气处理
银纳米粒子
水溶液中的金属离子
Mercury(编程语言)
选择性
纳米颗粒
酰胺
无机化学
核化学
离子
有机化学
材料科学
纳米技术
色谱法
催化作用
计算机科学
程序设计语言
作者
Pinki Sharma,Mohini Mourya,Deepika Choudhary,Manoj Goswami,Indra Kundu,M. P. Dobhal,Chandra Shekhar Pati Tripathi,Debanjan Guin
标识
DOI:10.1016/j.snb.2018.04.121
摘要
In this paper, we report a simple method for the optical detection of environmentally toxic mercury (II) ions (Hg2+) in water using chitosan capped silver nanoparticles (Ch–Ag NPs). The yellow colored aqueous solution of Ch-Ag NPs instantly (10 s) became colorless with addition of Hg2+ ions. Cu2+, and Fe3+ ions also produced colorless solution after 1 min. To overcome the Cu2+ and Fe3+ interference, thiol terminated chitosan was synthesized via amide coupling formation between amine group of chitosan and carboxylic acid group of 3-Mercaptopropanoic acid (3-MPA). The detailed study of selectivity, sensitivity, effect of interfering radicals, and response time confirmed that thiol terminated chitosan capped silver nanoparticles (Mod-Ch-Ag NPs) are highly selective and speedy for Hg2+ ions detection. The limit of detection was found to be 5 ppb. Furthermore, since the change in color with addition of mercury can be observed by naked eye, the developed nanosensor can also be utilized for real field applications. Hydrogel of Mod-Ch–Ag NPs was successfully synthesized and it was also found highly specific for Hg2+ ions. It was observed that separation of Hg2+ ions is also possible by simply changing the pH of the solution containing colorless Hg2+ with Mod-Ch-Ag NPs.
科研通智能强力驱动
Strongly Powered by AbleSci AI