化学
活化能
体积流量
分析化学(期刊)
扩散
废气
热力学
反应速率
色谱法
物理化学
催化作用
物理
有机化学
作者
Yoshinori Saito,Hisakuni Sato,Yukio Sakabe
出处
期刊:Journal of Chemical Engineering of Japan
[The Society of Chemical Engineers Japan]
日期:2008-01-01
卷期号:41 (5): 441-446
被引量:13
摘要
We investigated the use of Ba2TiO4 to remove CO2 from a flow gas at high temperatures. Experiments using a CO2/N2 gas and a vertical reaction tube showed that the CO2 concentration of the exit gas can be reduced to 1% or less at 500 to 800°C (and to even 0.1% or less at 600°C) when the space velocity (SV) of the flow is 2000 h–1. Also, the CO2 concentration changes for the gas mass flow at 700°C or lower. From the results of reaction rate analysis of Ba2TiO4 and CO2, at temperatures of 550°C and higher, the activation energy was 12.5 kJ/mol, indicating that this range is a diffusion-rate controlled area. The reaction rate had a linear correlation with the CO2 concentration from 500 to 800°C, and the estimated reaction degree was 0.96. These results indicate that Ba2TiO4 can effectively remove CO2 from exhaust gas at high temperatures.
科研通智能强力驱动
Strongly Powered by AbleSci AI