材料科学
锂(药物)
电解质
萃取(化学)
阴极
阳极
电池(电)
过氧化物
硅
氧气
相(物质)
化学工程
无机化学
物理化学
电极
热力学
有机化学
冶金
功率(物理)
化学
工程类
医学
物理
内分泌学
作者
KyuJung Jun,Lori A. Kaufman,Wangmo Jung,Byungchun Park,Chiho Jo,Tong-Kewn Yoo,Donghun Lee,Byungju Lee,Bryan D. McCloskey,Haegyeom Kim,Gerbrand Ceder
标识
DOI:10.1002/aenm.202301132
摘要
Abstract The use of a sacrificial cathode additive that contains a large amount of lithium is one potential solution to compensate for the irreversible capacity loss associated with next‐generation anodes such as silicon. Antifluorite‐type Li 6 CoO 4 has attracted attention as a potential cathode additive owing to its remarkably high theoretical lithium extraction capacity. However, the complex mechanism of lithium extraction as well as the oxygen loss from Li 6 CoO 4 is not well understood. A generalizable computational thermodynamics and experimental framework is presented to understand the lithium‐extraction pathway of Li 6 CoO 4 . It is found that one lithium per formula unit can be topotactically extracted from Li 6 CoO 4 , followed by an irreversible and nontopotactic phase transformation to Li 2 CoO 3 or LiCoO 2 depending on the temperature. The results show that peroxide species may form to charge‐compensate for Li extraction which is undesirable as this can lead to gas release during battery operation. It is suggested that charging Li 6 CoO 4 at an elevated temperature that the electrolyte can withstand, redirects the reaction pathway and prevents the formation of intermediate peroxide species making it an effective and stable sacrificial cathode additive.
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