In this study, sodium aluminum silicate inorganic polymer was synthesized by sol-gel method. The parameters affecting the polymer formation were also investigated. Polymers with optimal parameters have been applied to make high temperature resistant inorganic paints. Modified infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and X-ray diffraction (XRD) methods were used to investigate the characteristics of the paint film. Furthermore, the mechanical and mechanical properties of heat-resistant inorganic paints and their heat resistance were also investigated.