Construction of compostable packaging with antibacterial property and improved performance using sprayed coatings of modified cellulose nanocrystals

Increasing concerns about food safety and the environment have facilitated the development of eco-friendly antibacterial packaging. This study aimed to demonstrate a facile way to fabricate active packaging materials with modified cellulose nanocrystals (CNCs) and compare the effects of different modified CNCs on the performance of compostable materials. Polylactic acid (PLA) film was selected as a model, and CNCs were modified with methacrylamide, cetyltrimethylammonium bromide, and zinc oxide, respectively, and then applied on the surface of PLA films by spray-coating. All modified CNCs showed excellent antibacterial activity against S. aureus and E. coli (>99.999 %). The effects of different CNC modifications on the performance of PLA films were investigated. Compared to neat PLA films, PLA/CNC films exhibited improved mechanical strength with maintained flexibility, lower gas permeability, and faster compost disintegration rate, and extended the shelf life of wrapped pork samples from 3 days to >10 days. Therefore, this work will also facilitate the applications of PLA materials in eco-friendly packaging.