Simultaneous exfoliation/fluorination for the preparation of fluorinated exfoliated graphite with high power densities in primary lithium batteries

• Fluorinated expanded graphites were prepared using two routes. • High content of the (C 2 F)n structural type and a significant proportion of sp 2 carbons allow the electrochemical performance to be improved in primary Li battery. • Faradic yield close to 100% up to 6C discharge rates is achieved. • A good compromise between the energy and power densities is obtained. Fluorinated carbons combining accordion-like morphology, high content of (C 2 F) n phase (43%), and residual non-fluorinated carbons were synthetized by two routes, i.e. fluorination of expanded graphite and simultaneous exfoliation/fluorination of expandable graphite. The latter allows the synthesis in a one-step process to be achieved. Accordion-like morphology allows the accommodation of LiF without detrimental accumulation onto the fluorocarbon sheet edges during the discharge in primary lithium battery. The faradic yield is then close to 100 % up to a discharge rate of 6C. Residual sp 2 carbons (sub-fluorination) ensure the electron flux during the electrochemical process and enhance the power density (9828 W.Kg -1 ). High content of (C 2 F) n phase results in a flat galvanostatic discharge curve. The combination of those features results in a good compromise between energy and power densities, making fluorinated exfoliated graphite one of the best cathodes for primary lithium batteries.