水溶液
发光
光致发光
材料科学
镧系元素
聚合物
分子
制作
水溶液中的金属离子
纳米尺度
配位聚合物
纳米技术
化学工程
离子
无机化学
金属
物理化学
化学
有机化学
光电子学
冶金
复合材料
病理
工程类
医学
替代医学
作者
Weiting Yang,Jing Feng,Hongjie Zhang
摘要
Nanoscale Tb-active coordination polymers Tb(BTC)(H2O)6 were facilely, rapidly and environmentally-friendly fabricated at room temperature. The structures of the samples were confirmed by powder X-ray diffraction and elemental analyses, and the morphologies were characterized by SEM. The studies of the photoluminescence properties reveal that these nanostructured coordination polymers exhibit green emission, corresponding to the 5D4 → 7FJ transitions of the Tb3+ ions under UV light excitation, which represents highly selective and sensitive sensing for metal ions and acetone molecules in aqueous solution, and the probable sensing mechanisms were discussed.
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