Organic dye removal from aqueous solutions by hierarchical calcined Ni-Fe layered double hydroxide: Isotherm, kinetic and mechanism studies

Hierarchically porous nickel–iron-layered double hydroxide (NiFe-LDH) with a Ni2+/Fe3+ molar ratio of 3 was successfully synthesised through a simple hydrothermal route. After calcination at 400 °C, NiFe-LDH transformed into nickel–iron-layered double oxides (NiFe-LDO). The as-prepared samples were characterised through X-ray powder diffraction, field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and nitrogen adsorption. The calcined and uncalcined NiFe-LDH was used as adsorbents to remove Congo red (CR) dye in an aqueous solution. The equilibrium adsorption data of NiFe-LDH and NiFe-LDO samples were well fitted to Langmuir model and were characterised by excellent adsorption capacities of 205 and 330 mg/g, respectively. Pseudo-second-order kinetic and intra-particle diffusion models indicated that CR was well adsorbed on the adsorbent. The underlying adsorption mechanism was investigated and observed as anion exchange and reconstruction.