化学
对苯二甲酸
荧光
超分子化学
堆积
发光
三元运算
咪唑
热液循环
结晶学
小型商用车
立体化学
晶体结构
金属有机骨架
物理化学
有机化学
吸附
物理
光电子学
量子力学
地震学
计算机科学
聚酯纤维
程序设计语言
地质学
作者
Xiangwen Wang,Lianshe Fu,Guang‐Hua Cui
出处
期刊:Polyhedron
[Elsevier]
日期:2023-11-01
卷期号:244: 116624-116624
被引量:2
标识
DOI:10.1016/j.poly.2023.116624
摘要
Four new ternary Cd(II) coordination polymers (CPs) based on rarely-used 2-(pyridin-2-yl)-1-(pyridin-3-ylmethyl)-1H-benzo[d]imidazole (L) were synthesized via hydrothermal method, namely {[Cd(L)(H2DOBDC)]·H2O}n (1), {[Cd(L)(TP)]·2H2O}n (2), [Cd2(L)(DCTP)2(H2O)]n (3) and {[Cd2(L)(NDA)2]·H2O}n (4) (H4DOBDC = 2,5-dihydroxy terephthalic acids, H2TP = terephthalic acid, H2DCTP = 2,5-dichloroterephthalic acid and H2NDA = 1, 4-naphthalenedicarboxylic acid). 1 and 2 are 4-connected 2D sql layers, in which 2 is further expanded into a 3D supramolecular network by π − π stacking interaction, while 3 and 4 exhibit three-dimensional frameworks with unusual topology. 1 and 3/2 and 4 can act as dual-functional fluorescent sensors for the sensing of Hg2+/Co2+and chlortetracycline (CTC) with response times of 30 s for Hg2+/Co2+ and 20 s for CTC, respectively, in which 2 and 3 as promising fluorescence probes for analytes with detection limits of 1.44 and 0.91 μmoL/L, 3.34 and 0.66 μmoL/L, respectively. The fluorescence sensing mechanism was discussed in detail.
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