纳米笼
材料科学
阳极
复合数
碳化
碳纤维
化学工程
纳米技术
复合材料
电极
化学
扫描电子显微镜
生物化学
物理化学
工程类
催化作用
作者
Xia Qiu,Lifeng Shi,Zihan Xu,Junchao Qian,Ming Song,Limei Sun,Xuena Xu,Xiaomin Yan,Yanzhen Fu,Jizhen Ren,Weihua Zhuang,Quanchao Zhuang,Zhicheng Ju,Yaxin Chen
标识
DOI:10.1016/j.jallcom.2023.172539
摘要
Graphitic nanocarbon possesses fast potassium storage capability at low voltage. However, a significant abundance of exposed edge surfaces and defects of graphitic nanocarbon would lead to a substantial number of irreversible reactions, thereby reducing the cyclic stability. Here, the edge defects of graphitic carbon nanocages (GCC) were protected by pitch-based disordered carbon shell to enhance the long-term cyclic stability. The mixture of GCC and pitch was compressed to ensure the full contact of the two components followed by carbonization at 1100 °C. The composite structure can protect the edge and defect of GCC to reduce the irreversible reactions. Moreover, the developed three-dimensional network can form interconnected paths to enhance the electron transfer. Benefiting from this structure, the composite anode achieves high reversible capacity below 1 V (214.1 mAh g−1 at 0.1 C) and high-rate (138.9 mAh g−1 at 1 C). Additionally, the composite anode exhibits higher cyclic stability (96.2% capacity retention from the first to the 80th cycle) than that of GCC (29.8%). This work presents a rational strategy to achieve the edge defect protection of graphitic nanocarbon, thereby facilitate the application of graphitic nanocarbon materials in potassium-ion batteries.
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