Multicomponent Synthesis of S ‑Vinyl Dithiocarbamates Using Vinyl Sulfonium Salts with CS 2 and Amines

Abstract A method for synthesizing dithiocarbamates via the ring‐opening of vinyl sulfonium salts, employing CS 2 and amines has been presented. The transformation can be performed rapidly at room temperature in ambient air without any additives. Additionally, the protocol features an extensive substrate range and simple reactive operations and affords the dithiocarbamates in a remarkably short time and elevated yields.