超级电容器
假电容器
储能
杂原子
纳米技术
纳米材料
钴
材料科学
电化学
化学
功率(物理)
电极
戒指(化学)
冶金
有机化学
物理化学
物理
量子力学
作者
Lin Peng,Dan Wang,Jibiao Wang,Yuan Cheng,Xiaosong Li,Wenchang Wang,Naotoshi Mitsuzaki,Shuyong Jia,Zhidong Chen
摘要
As one of the most promising energy storage devices, supercapacitors exhibit a higher power density than batteries. However, its low energy density usually requires high-performance electrode materials. Although the RuO2 material shows desirable properties, its high cost and toxicity significantly limit its application in supercapacitors. Recent developments demonstrated that Co-based materials have emerged as a promising alternative to RuO2 for supercapacitors due to their low cost, favorable redox reversibility and environmental friendliness. In this paper, the morphological control and performance engineering of Co-based materials are systematically reviewed. Firstly, the principle of supercapacitors is briefly introduced, and the characteristics and advantages of pseudocapacitors are emphasized. The special forms of cobalt-based materials are introduced, including 1D, 2D and 3D nanomaterials. After that, the ways to enhance the properties of cobalt-based materials are discussed, including adding conductive materials, constructing heterostructures and doping heteroatoms. Particularly, the influence of morphological control and modification methods on the electrochemical performances of materials is highlighted. Finally, the application prospect and development direction of Co-based materials are proposed.
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