荧光粉
温度计
兴奋剂
分析化学(期刊)
晶体结构
材料科学
荧光
磷酸盐
结构精修
化学
矿物学
光电子学
光学
结晶学
物理
有机化学
量子力学
色谱法
作者
Baochen Wang,Shaobo Sun,Zeqi Li,Zongwang Li,Weiwei Lin,Chao Zeng,Yicen Liu,Ruiyu Mi
标识
DOI:10.1016/j.jre.2023.03.001
摘要
Rare earth co-doped phosphor for fluorescence intensity ratio (FIR) thermometer has gained increasing attention in recent years. Herein, the novel Tb3+ and Eu3+ co-doped K3SrBi(P2O7)2 (KSBP) phosphate phosphors were reported. The crystal structure of the title phosphor was determined using Rietveld refinement and proved to have a three-dimensional structure. The time-resolved spectroscopy reveals that there is almost no energy transfer between Tb3+ and Eu3+. More importantly, Tb3+ and Eu3+ emissions show different thermal quenching behaviors, which claims the potential of this material for application in optical thermometer. The FIR of the typical KSBP:0.02Tb3+,0.04Eu3+ sample demonstrates a polynomial relationship as a function of temperature and the absolute and relative sensitivity are 0.025 K–1 and 0.59%/K, respectively. In general, our study reports a novel and potential KSBP:Tb3+,Eu3+ phosphate phosphor that is promising for use in high-sensitive FIR thermometers.
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