超级电容器
阳极
材料科学
电容
阴极
电解质
电池(电)
电极
电化学
化学工程
比能量
钒
储能
五氧化二铁
光电子学
功率密度
电容器
电气工程
化学
功率(物理)
冶金
电压
物理化学
工程类
物理
量子力学
作者
Xingxing Li,Yanan Ma,Yue Yang,Guosheng Li,Chuankun Zhang,Minglei Cao,Yong‐Chen Xiong,Jintao Zou,Yongheng Zhou,Yihua Gao
标识
DOI:10.1016/j.cej.2021.130965
摘要
In recent years, the metal ion hybrid micro-supercapacitor (MSC) comprised of the battery-type Faradaic cathode based electrode and capacitor-type anode based electrode, can realize both high power and energy density, which becomes one of the most hottest areas of energy device. Herein, we demonstrated a zinc-ion hybrid micro-supercapacitor (ZIHMSC) by designing a Ti3C2Tx MXene based electrode as capacitor-type anode and vanadium pentoxide (V2O5) based electrode as battery-type cathode. In addition, the polyacrylamide (PAM) hydrogel where ZnSO4 dissolved was chosen as the electrolyte, which effectively avoids the security risks, unlike other hybrid MSC based on the organic electrolytes. Meanwhile, the flexible ZIHMSC also exhibits well electrochemical properties, displaying a remarkable capacitance (129 mF cm−2 under 0.34 mA cm−2), high energy density (48.9 μWh cm−2 at 673 μW cm−2) and well-cycle stability (retaining ~ 77% capacitance after 10,000 cycles). This work supports a prospective routine for constructing the new-generation flexible micro-energy storage systems.
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