Investigation of high potential corrosion protection with titanium carbonitride coating on 316L stainless steel bipolar plates

In order to improve the durability of stainless steel bipolar plates at high potential during the start-up/shut-down process of proton exchange membrane fuel cell (PEMFC), TiN and TiCN coatings with different C element contents are deposited on the 316L stainless steel substrates by using Closed Field Unbalanced Magnetron Sputter Ion Plating. The electrochemical test results show that the TiCN-2sccm sample possesses excellent corrosion resistance compared to other samples. The results of interfacial contact resistance (ICR) measurements show that the minimum ICR value of the TiCN-2sccm sample is 10 mΩ cm2, which meets the Department of Energy targets.