牡蛎
检出限
化学
电感耦合等离子体质谱法
萃取(化学)
环境化学
氯化物
色谱法
质谱法
遗传算法
铅污染
铅(地质)
海水
污染
渔业
海洋学
生态学
地质学
生物
有机化学
地貌学
作者
Yiquan Chen,Limei Huang,Weihua Wu,YaJuan Ruan,Zujian Wu,Zhimin Xue,FengFu Fu
标识
DOI:10.1002/elps.201300410
摘要
We herein reported a environment‐friendly microwave‐assisted extraction used to extract trace lead compounds from marine animals and a ultrasensitive method for the analysis of Pb 2+ , trimethyl lead chloride (TML) and triethyl lead chloride (TEL) by using CE‐ICP‐MS. The extraction method is simple and has a high extracting efficiency. It can be used to completely extract both inorganic lead and organolead in marine animal samples without altering its species. The analytical method has a detection limit as low as 0.012–0.084 ng Pb/mL for Pb 2+ , TML, and TEL, and can be used to determine ultratrace Pb 2+ , TML, and TEL in marine animals directly without any preconcentration. With the help of above methods, we have successfully determined Pb 2+ , TML, and TEL in clam and oyster tissue within 20 min with a RSD ( n = 6) < 5% and a recovery of 91–104%. Our results showed that Pb 2+ was the main species of lead in clam and oyster, and organolead (TML) was only found in oyster. The proposed method provides a realistic approach for the accurate evaluation of lead pollution in seafood.
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