环氧乙烷
碱金属
拉曼光谱
聚合物
盐(化学)
离子键合
无机化学
氧化物
高分子化学
金属
电解质
红外光谱学
化学
材料科学
物理化学
离子
有机化学
物理
电极
共聚物
光学
作者
B. L. Papke,Mark A. Ratner,Duward F. Shriver
标识
DOI:10.1016/0022-3697(81)90030-5
摘要
Complexes of poly(ethylene oxide) (PEO), with various alkali metal salts are known to exhibit ionic conductivities which exceed 10−5(Ωcm)−1 at moderate temperatures. We have employed IR and Raman spectroseopy to study well characterized samples of the following polymer-salt complexes: PEO·NaBr, PEO·NaI, PEO·NaSCN, PEO·NaBF4, PEO·NaCF3SO3, PEO·KSCN, PEO·RbSCN and PEO·CsSCN. Cation-dependent vibrational bands observed in the far IR and M-On symmetric stretching bands observed in the Raman support a cation-oxygen atom interaction, and indicate the polyether chain may wrap around the cations. In particular, NaX and KX complexes of PEO are believed to have a helical configuration for the polymer which differs from that of pure PEO. Some general rules are presented for polymer-salt complex formation.
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