Photochemically Excited, Pulsating Janus Colloidal Motors of Tunable Dynamics

Spontaneous periodicity is widely found in many biological and synthetic systems, and designing colloidal motors that mimic this feature may not only facilitate our understanding of how complexity emerges but also enable applications that benefit from a time-varying activity. However, there is so far no report on a colloidal motor system that shows controllable and spontaneous oscillation in speeds. Inspired by previous studies of oscillating silver microparticles, we report silver-poly(methyl methacrylate) microsphere Janus colloidal motors that moved, interacted with tracers, and exhibited negative gravitaxis all in an oscillatory fashion. Its dynamics, including pulsating speeds and magnitude, as well as whether moving forward in a pulsating or continuous mode, can be systematically modulated by varying chemical concentrations, light intensity, and the way light was applied. A qualitative mechanism is proposed to link the oscillation of Janus colloidal motors to ionic diffusiophoresis, while nonlinearity is suspected to arise from a sequence of autocatalytic decomposition of AgCl and its slow buildup in the presence of H2O2 and light. The generation of light-absorbing Ag nanoparticles is suspected to be the key. This study therefore establishes a robust model system of chemically driven, oscillatory colloidal motors with clear directionality, good tunability, and an improved mechanism, with which complex, emergent phenomena can be explored.