膜
共价键
纳米技术
共价有机骨架
材料科学
气体分离
多孔性
连接器
制作
化学
计算机科学
有机化学
病理
复合材料
操作系统
医学
替代医学
生物化学
作者
Tahir Rasheed,Sardaraz Khan,Tauqir Ahmad,Nisar Ullah
标识
DOI:10.1002/tcr.202200062
摘要
Abstract Covalent organic frameworks (COFs) are a promising class of porous crystalline materials made up of covalently connected and periodically protracted network topologies through organic linkers. The tailorability of organic linker and intrinsic structures endow COFs with a tunable porosity and structure, low density, facilely‐tailored functionality, and large surface area, attracting increasing amount of interests in variety of research areas of membrane separations. COF‐based membranes have spawned a slew of new research projects, ranging from fabrication methodologies to separation applications. Herein, we tried to emphasis the major developments in the synthetic approaches of COFs based membranes for a variety of separation applications such as, separation of gaseous mixtures, water treatment as well as separation of isomeric and chiral organic compounds. The proposed methods for fabricating COF‐based continuous membranes and columns for real world applications are also thoroughly explored. Finally, a viewpoint on the future directions and remaining challenges for COF research in the area of separation is provided.
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