Effects of an Electrical Double Layer and Tribo-Induced Electric Field on the Penetration and Lubrication of Water-Based Lubricants

Understanding the effects of electrical double layers (EDL) and tribo-induced electric fields on the electroosmotic behaviors of lubricants is important for developing high-performance water-based lubricants. In this study, EDL conductivities of aqueous lubricants containing a surfactant of 3-[(3-cholamidopropyl)-dimethylammonio]-1-propanesulfonate (CHAPS) or cetyltrimethylammonium bromide (CTAB) were analyzed. The interfacial zeta potentials of the synthesized lubricants and Al2O3 ceramic-alloy steel contacts were measured, and frictional potentials of ceramic and steel surfaces were determined using a modified ball-on-disc configuration. The distribution characteristics of the tribo-induced electric field of the ceramic-steel sliding contact were numerically analyzed. The electroosmotic behaviors of the lubricants were investigated using a four-ball configuration. It was found that an EDL and tribo-induced electric field was a crucial enabler in stimulating the electroosmosis of lubricants. Through altering EDL structures, CHAPS enhanced the electroosmosis and penetration of the water-based lubricant, thus resulting in improved lubrication.