氢化酶
光催化
催化作用
制氢
人工光合作用
电子转移
光化学
营业额
材料科学
半导体
化学
化学工程
光电子学
生物化学
工程类
作者
Fuyu Wen,Xiuli Wang,Lei Huang,Guijun Ma,Jinhui Yang,Can Li
出处
期刊:Chemsuschem
[Wiley]
日期:2012-05-01
卷期号:5 (5): 849-853
被引量:84
标识
DOI:10.1002/cssc.201200190
摘要
Photo opportunity: A highly efficient and stable hybrid artificial photosynthetic H(2) evolution system is assembled by using a semiconductor (ZnS) as light-harvester and an [Fe(2)S(2)] hydrogenase mimic ([(μ-SPh-4-NH(2) )(2) Fe(2) (CO)(6)]) as catalyst for H(2) evolution. Photocatalytic H(2) production is achieved with more than 2607 turnovers (based on [Fe(2)S(2)]) and an initial turnover frequency of 100 h(-1) through the efficient transfer of photogenerated electrons from ZnS to the [Fe(2)S(2)] complex.
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