线性二色性
结晶学
材料科学
各向异性
外延
价(化学)
八面体
凝聚态物理
分析化学(期刊)
物理
晶体结构
光学
圆二色性
化学
纳米技术
图层(电子)
量子力学
色谱法
作者
C. Aruta,G. Ghiringhelli,A. Tebano,Norberto Boggio,N. B. Brookes,P. G. Medaglia,G. Balestrino
出处
期刊:Physical Review B
[American Physical Society]
日期:2006-06-27
卷期号:73 (23)
被引量:119
标识
DOI:10.1103/physrevb.73.235121
摘要
Strain induced anisotropy in the electronic properties of ${\mathrm{La}}_{0.7}{\mathrm{Sr}}_{0.3}\mathrm{Mn}{\mathrm{O}}_{3}$ thin films was investigated by x-ray absorption spectroscopy at the Mn $2p$ and O $1s$ edges. Films on (100) $\mathrm{Sr}\mathrm{Ti}{\mathrm{O}}_{3}$ and (100) $\mathrm{La}\mathrm{Al}{\mathrm{O}}_{3}$ substrates were grown by pulsed laser deposition with in situ reflection high energy electron diffraction diagnostic. At both absorption edges, clear features related to different anisotropic lattice strain effects as a function of the substrate were observed. On the average a negative (positive) linear dichroism was obtained for films grown under in-plane tensile (compressive) epitaxial strain conditions. Indeed, the structural macroscopic distortion induced by the substrate is responsible of the octahedra distortions with the resulting stabilization of ${x}^{2}\text{\ensuremath{-}}{y}^{2}$ $(3{z}^{2}\text{\ensuremath{-}}{r}^{2})$ orbitals. Enhanced linear dichroism at the Mn $2p$ edge in very thin films, only a few unit cells thick, is in agreement with a fully strained state which favors the formation of orbital ordered phase regions.
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