Improving the Selectivity of ZIF-8/Polysulfone-Mixed Matrix Membranes by Polydopamine Modification for H2/CO2 Separation

Gas separation membranes are essential for the capture, storage, and utilization (CSU) of CO₂, especially for H₂/CO₂separation. However, both glassy and rubbery polymer membranes lead a relatively poor selectivity for H₂/CO₂ separation because the differences in kinetic diameters of these gases are small. The present study establishing the mixed matrix membranes (MMMs) consist of a nano-sized zeolitic imidazolate frameworks (ZIF-8) blended with the polysulfone (PSf) asymmetric membranes. The gas transport properties (H₂, CO₂, N₂, and CH₄) of MMMs with a ZIF-8 loading up to 10 wt% were tested and showing significant improvement on permeance of the light gases (e.g., H₂ and CO₂). Moreover, the depositional polydopamine (PDA) layer further enhanced the ideal H₂/CO₂ selectivity, and the PDA-modified MMMs approach the Robeson upper bound of H₂/CO₂ separation membranes. Hence, the PDA post-modification strategy can effectively repair the defects of MMMs and improved the H₂/CO₂selectivity.