超级电容器
石墨烯
材料科学
电容
异质结
电极
功率密度
复合数
电化学
储能
纳米技术
氧化物
化学工程
光电子学
复合材料
化学
冶金
功率(物理)
量子力学
物理
工程类
物理化学
作者
Xinliang Feng,Jing Ning,Dong Wang,Jincheng Zhang,Maoyang Xia,Ying Wang,Yue Hao
标识
DOI:10.1016/j.jallcom.2019.152625
摘要
Supercapacitors, as a clean and sustainable power supply, have been a popular subject of research in the field of energy storage owing to their excellent electrochemical performance. As an important part of supercapacitors, electrode materials and structures have been continuously designed and improved. This study presents a facile synthesis of an N-doping of graphene/NiMoO4 (NG/NiMoO4) heterostructure for electrochemical supercapacitors. By combining excellent conductivity, large specific surface area of graphene, and reversible redox of metal oxide, this hybrid composite exhibits an ultrahigh specific capacitance of 1913 F/g at 1 A/g. Using NG/NiMoO4 as positive electrode and active carbon as negative electrode, an asymmetric supercapacitor was assembled. The device exhibits a high capacitance of 62.5 F/g at 0.5 A/g, a maximum energy density of 22.2 Wh/kg at the power density of 400 W/kg, and excellent cycling stability (94.2% retention after 5000 cycles). The results demonstrate that the NG/NiMoO4 composite is a promising electrode material for supercapacitors in energy storage applications.
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