Rational construction Ag/LiF/sulfide rich protective layer for remarkably enhancing the stability of Li metal anodes

Li metal is a promising anode material for high-energy–density batteries due to its high theoretical capacity and low redox potential. However, both the uncontrolled Li dendrite growth and unstable solid electrolyte interphase (SEI) layer restricts its large-scale practical applications. Herein, an artificial protective layer consisting of Ag nanoparticles, lithium fluoride (LiF) and sulfide are innovatively designed and fabricated via the in-situ chemical reaction between Ag(I) trifluoromethylthiolate (AgSCF3) and Li metal. Density functional theory (DFT) results indicate that Ag nanoparticles has a high binding energy with Li atom and LiF/sulfide have wide band gap, which would provide plenty of nucleation sites for Li+ and reduce the direct contact between inner Li metal and the electrolyte. The co-existence of Ag and LiF/sulfide can produce a strong synergistic effect, and this is confirmed by the systematical comparison with single modified Ag-Li and double modified F/S-Li anodes. Benefitting from this synergistic effect, the Ag/F/S-Li symmetrical cells can stably work for 2000 h with low-voltage hysteresis at current density of 1 mA cm−2. Full cells assembled with LiCoO2 (LCO) and LiFePO4 (LFP) cathodes displays much better long‐term cycle performance when the Ag/F/S-Li anode is applied. Furthermore, this Ag/F/S-Li modification can significantly enhance discharge capacity, rate performance, as well as energy density of Li(or LiB alloy)||MnO2 primary cells. This promising work promotes the practical application of Li metal and provides new insight into the protective layer design in stable Li metal batteries.