UHPC has been found to have excellent freeze–thaw durability in cold regions. Previous UHPC testing performed has mostly focused on concrete with compressive strength above 21 ksi (145 MPa). In this study, testing was conducted to determine at what strength level concrete transitions to provide excellent freeze–thaw (F–T) performance. Non-proprietary concrete samples were made for freeze–thaw durability from four different concrete mixture designs: 12–15 ksi, 15–18 ksi, 18–21 ksi, and 21+ ksi (83–145+ MPa), and these were tested according to ASTM C666, using 1.5% steel fibers. The samples were made for three different curing regimens: limewater curing in a fog room, simulated precast curing, and steam curing. Low-temperature differential scanning calorimetry (DSC) and mercury intrusion porosimetry (MIP) tests were carried out to reveal the freeze–thaw mechanism of the concrete samples. All mixtures with compressive strength above 15 ksi (103 MPa) performed excellent in freeze–thaw testing with no damage seen. Steam curing was found to negatively affect the freeze–thaw performance at the lowest strength level tested.