环氧树脂
材料科学
层状结构
纳米复合材料
复合材料
电磁屏蔽
质量分数
热稳定性
电磁干扰
电磁干扰
电子工程
化学工程
工程类
作者
Lei Wang,Zhonglei Ma,Hua Qiu,Yali Zhang,Ze Yu,Junwei Gu
标识
DOI:10.1007/s40820-022-00949-8
摘要
Abstract High‑efficiency electromagnetic interference (EMI) shielding materials are of great importance for electronic equipment reliability, information security and human health. In this work, bidirectional aligned Ti 3 C 2 T x @Fe 3 O 4 /CNF aerogels (BTFCA) were firstly assembled by bidirectional freezing and freeze-drying technique, and the BTFCA/epoxy nanocomposites with long-range aligned lamellar structures were then prepared by vacuum-assisted impregnation of epoxy resins. Benefitting from the successful construction of bidirectional aligned three-dimensional conductive networks and electromagnetic synergistic effect, when the mass fraction of Ti 3 C 2 T x and Fe 3 O 4 are 2.96 and 1.48 wt%, BTFCA/epoxy nanocomposites show outstanding EMI shielding effectiveness of 79 dB, about 10 times of that of blended Ti 3 C 2 T x @Fe 3 O 4 /epoxy (8 dB) nanocomposites with the same loadings of Ti 3 C 2 T x and Fe 3 O 4 . Meantime, the corresponding BTFCA/epoxy nanocomposites also present excellent thermal stability ( T heat-resistance index of 198.7 °C) and mechanical properties (storage modulus of 9902.1 MPa, Young's modulus of 4.51 GPa and hardness of 0.34 GPa). Our fabricated BTFCA/epoxy nanocomposites would greatly expand the applications of MXene and epoxy resins in the fields of information security, aerospace and weapon manufacturing, etc.
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