Cobalt-Catalyzed Enantioselective Radical Hydroamination of Alkenes with N-Fluorobenzenesulfonimides: Theoretical Insight of Enantio-Determining SN2-like Reductive Elimination

The cobalt-catalyzed enantioselective radical hydroamination of alkenes with N-fluorobenzenesulfonimides has been systematically investigated using density functional theory (DFT) calculations. The favorable reaction mechanism consists of six key processes: halogen atom...