石膏
碳酸钙
硬石膏
饱和(图论)
石油工程
硫酸盐
锶
化学
碳酸盐
矿物学
溶解度
钙
钡
缩放比例
无机化学
地质学
数学
有机化学
古生物学
组合数学
几何学
作者
J.E. Oddo,Mason B. Tomson
出处
期刊:SPE production & facilities
[Society of Petroleum Engineers]
日期:1994-02-01
卷期号:9 (01): 47-54
被引量:194
摘要
Summary Predicting potential scaling problems can be difficult, and numerous saturation indices and computer algorithms have been developed to determine if, when, and where scaling will occur. The Langelier, Stiff-Davis, and the Oddo-Tomson saturation indices, all widely used in the oil field, are compared and contrasted relative to calcium carbonate scale. New saturation indices for barium, strontium, and calcium sulfate scale formation are introduced and discussed, along with an updated version of the Oddo-Tomson calcium carbonate index. An updated version of the CaCO3 saturation index is presented that includes correction terms for fugacity effects and changes in the solubility of CO2 in oil and gas wells as functions of temperature, pressure, water cut, and hydrocarbons present. The CaCO3 saturation index does not require a measured pH and can accommodate the presence of weak acids, such as H2S, and weak organic acids in the system. The sulfate scale prediction methods (for gypsum, hemihydrate, and anhydrite) are easy to use, reliable, and designed for field use by an operator who may be untrained in chemistry. The prediction methods can be applied to any production well where calcium carbonate, calcium sulfate, strontium sulfate, or barium sulfate scale occurs.
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