Designed poly(ether-imide)s and fluoro-copoly(ether-imide)s: Synthesis, characterization and their film properties

Two series of amorphous fluoro-poly(ether-imide) (6F-PEI) and one series of fluoro-coploy(ether-imide) (6F-CoPEI) polymers based on 2,2′-bis(3,4-dicarboxyphenyl) hexafluropropane dianhydride (6FDA) and di-ether-containing diamines: 1,2′-bis(4-aminophenoxy)benzene (o-BAPOB) and 4,4′-bis(4-aminophenoxy)diphenyl sulfone (p-SED) were synthesized. The solution properties, chemical resistance, thermal stability, mechanical properties, thermo-oxidative and hydrolytic stability of selected 6F-PEIs and 6F-CoPEIs were studied. The dielectric constant (ɛ′) values of 6F-PEI and 6F-CoPEI were estimated by additive group contribution calculation using mathematical equations defined by the Lorentz–Lorenz's theory and the Vogel's theory, and by Vora–Wang equations, respectively. These polymers not only showed excellent electrical properties but also excellent long-term thermo-oxidative stability and reduced water absorption relative to non-fluorinated polyimides. The estimated dielectric constant of these polymers (ɛ′ < 3.15) were lower than those of commercially available poly(ether-imide) ULTEM®1000 and polyimides Kapton®H, respectively at 1 kHz. The analytical results are summarized and discussed.