尖晶石
阴极
电解质
材料科学
氧化还原
草酸盐
氧气
空位缺陷
化学工程
容量损失
铁质
相(物质)
表面改性
离子
阳极
无机化学
电极
化学
冶金
物理化学
结晶学
有机化学
工程类
作者
Zhengcheng Ye,Bin Zhang,Ting Chen,Zhenguo Wu,Daqiang Wang,Wei Xiang,Yan Sun,Yuxia Liu,Yang Liu,Jun Zhang,Yang Song,Xiaodong Guo
标识
DOI:10.1002/anie.202107955
摘要
release, prevents electrolyte corrosion, and promotes Li-ion diffusion. In addition, the surface doping of Fe-ion can further stabilize the structure. Accordingly, the treated Feox-2 % cathode exhibits superior capacity retention of 86.4 % and 85.5 % at 1 C and 2 C to that (75.3 % and 75.0 %) of the pristine sample after 300 cycles, respectively. Then, the voltage fading is significantly suppressed to 0.0011 V per cycle at 2 C especially. The encouraging results may play a significant role in paving the practical application of Li-rich layered oxides cathode.
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