化学
亲核细胞
阳离子聚合
吡啶
碘
药物化学
高分子化学
有机化学
催化作用
作者
Scott Wilcox,Daniel Sethio,Jas S. Ward,Antonio Frontera,Roland Lindh,Kari Rissanen,Máté Erdélyi
摘要
The interaction of a [bis(pyridine)iodine(I)]+ cation with a [bis(pyridine)silver(I)]+ cation, in which an iodonium ion acts as a nucleophile by transferring electron density to the silver(I) cation, is reinvestigated herein. No measurable interaction is observed between the cationic species in solution by NMR; DFT reveals that if there is an attractive interaction between these complexes in solution, it is dominantly the π-π interaction of pyridines.
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