化学
热力学
维里系数
一氧化碳
状态方程
甲醇
化学平衡
维里定理
巴(单位)
理想气体
氢
物理化学
催化作用
有机化学
物理
量子力学
银河系
气象学
作者
G.H. Graaf,P.J.J.M. Sijtsema,Eize Stamhuis,G.E.H. Joosten
标识
DOI:10.1016/0009-2509(86)80019-7
摘要
The chemical equilibria of the methanol reaction and the water—gas shift reaction, starting from carbon monoxide, carbon dioxide and hydrogen, were studied in a fixed-bed catalytic reactor at P = 10–80 bar and T = 200–270°C. It was found that the chemical equilibria could be described very well by thermochemical data based on ideal gas behaviour in combination with a correction for the non-ideality of the gas mixture as predicted by the Soave—Redlich—Kwong equation of state. This correction for non-ideality results in significantly better agreement with experimental data than a correction based on the original Redlich—Kwong equation of state, the Peng—Robinson equation of state, the virial equation truncated after the second virial coefficient, Lewis and Randall's rule, or not correcting at all for non-ideality, thus assuming ideal gas behaviour.
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