The fabrication and characterisation of surimi gel modified by konjac glucomannan with the different hydrolysis degree

水解 葡甘露聚糖 傅里叶变换红外光谱 明胶 流变学 热稳定性 共价键 食品科学 化学 肌原纤维 氢键 动态力学分析 化学工程 材料科学 聚合物 分子 有机化学 复合材料 工程类 生物化学
作者
Shichen Zhu,Chuanshuang Wei,Yan Jin,Yuan Feng,Qing Yang,Zhengpeng Wei,Shulai Liu,Shiliang Jia,Yuting Ding,Xuxia Zhou
出处
期刊:International Journal of Food Science and Technology [Wiley]
卷期号:58 (2): 766-776 被引量:8
标识
DOI:10.1111/ijfs.16228
摘要

Summary The gel performance of surimi‐based products is indispensable technological attribute responsible for their high popularity. Here, surimi gels with tunable gel properties were successfully fabricated based on the double network theory. Konjac glucomannan (KGM) hydrolysed for various periods (0, 5, 15, 30, 60 and 90 min) was introduced into surimi systems. Corresponding structural characterisations including FTIR, XRD, SDS‐PAGE and grafting degree assessment, were conducted to confirm the presence of double crosslinking reactions. Furthermore, the gel strength, dynamic rheology, thermal stability and in vitro digestibility of the surimi gels were investigated. Red shifts in the amide A band and an increase in relative intensity indicated that hydrogen bonding existed in the complex systems, according to the FTIR spectra. The XRD patterns suggested that the crystalline structures were weakened by interfering with the protein chain arrangement due to the Maillard reaction. In addition, SDS‐PAGE and o‐phthalaldehyde (OPA) assays also confirmed that myofibrillar protein and hydrolysed KGM were partially linked by covalent bonding. The SK‐2 group showed the greatest mechanical strength and lowest digestibility amongst all groups due to its dense hierarchical structure. This work may provide inspiration for the design and development of surimi gels with improved gel properties via microarchitectural modulation.
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