Back-Contact Perovskite Solar Cell Modules Fabricated via Roll-to-Roll Slot-Die Coating: Scale-Up toward Manufacturing

We fabricate a type of back-contact perovskite solar cell based on 1.5 μm-width grooves that are embossed into a plastic film whose opposing "walls" are selectively coated with either n- or p-type contacts. A perovskite precursor solution is then deposited into the grooves, creating individual photovoltaic devices. Each groove device is series-connected to its neighbors, creating minimodules consisting of hundreds of connected grooves. Here, we report on the fabrication of groove-based devices using slot-die coating to deposit the perovskite precursor and explore the structure of the perovskite in the grooves using a range of microscopy and spectroscopy techniques. Significantly, our devices do not contain any expensive or scarce elements such as indium, indicating that this technology is both sustainable and low-cost. Furthermore, all coating processes explored here were performed using roll-to-roll processing techniques. Our technology is therefore completely scalable and is consistent with high-throughput, low-cost manufacturing.