生物炭
碳化
水溶液
纳米材料
催化作用
表面改性
纳米颗粒
化学工程
化学
胶体金
氢
材料科学
热解
纳米技术
吸附
有机化学
物理化学
工程类
作者
Renata Pereira Lopes,Qiuxia Zhao,Sergio Moya,Marta Martínez Moro,Didier Astruc
标识
DOI:10.21577/0103-5053.20230122
摘要
Biochar is a material of great ecological interest obtained from the carbonization of biomass. Its structure is composed of graphene-like aggregates, and it contains useful functional groups such as carboxyl. Using these groups, biochar functionalization with triazole groups that improve support characteristics has been achieved to anchor and stabilize catalytically active gold nanoparticles (Au NPs). The Au NPs obtained were homogeneously distributed under biochar, with a size of 7.7 ± 3.5 nm. The efficiency of the nanomaterial was shown in nanogold-catalyzed hydrogen evolution from an aqueous solution containing B2(OH)4, with a maximum hydrogen generation of 715 mLH2 g-1 min-1 under optimized conditions (0.070 mmol of Au NPs and 0.300 mol L-1 of NaOH). This nanomaterial showed excellent efficiency in four successive catalytic cycles.
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