Durable water- and oil-repellent textiles without long- or short-chain perfluoroalkylated substances

For decades, the water and oil repellency of textiles was achieved using long-chain (CnF2n+1, n ≥ 7) perfluoroalkyl substances (PFAS). However, due to their proven bioaccumulative nature and toxic impacts on the environment and human health, these substances have been phased out of industrial production and/or legally banned in many countries. There is some evidence that a shorter carbon chain leads to less bioaccumulation and toxicity, and accordingly short-chain PFAS have been widely used as a replacement in recent years. Nevertheless, short-chain PFAS exhibit inferior surface properties due to their less crystalline and more loosely packed polymer chains, as compared to their long-chain counterparts. Moreover, surface properties become worse with decreasing chain length. Here we develop an alternative method for obtaining durable water and oil repellency on a nylon fabric using a liquidlike perfluoropolyether (PFPE) brush coating. The coating demonstrates excellent water and oil repellency, on par with the banned long-chain PFAS finishes, although its longest PFAS degradation product would have a chain length of L = 3, i.e. an ultra-short-chain PFAS. The PFPE-treated nylon exhibits superior surface properties compared to state-of-the-art, short-chain PFAS finished fabrics used in industry currently, even after laundering and 10,000 cycles of abrasion. The comfort of the treated fabrics is also maintained. The PFPE coatings developed here could replace the toxic, short-chain PFAS in use worldwide today.