The electrochemical behavior of the new biferrocenamine-based receptor(FcL) and its electrochemical responses to metal ions(Ca~2+,Mg~2+,Cu~2+,Zn~2+ and Ni~2+) has been investigated by cyclic voltammetry.Moreover,in acetonitrile solution its kinetics parameters of electrochemistry were obtained by cyclic voltammetry(CV)、chronocoulometry(CC) and normal pulse voltammetry,too.