Water Recovery Rate in Short-Circuited Closed-Cycle Operation of Flow-Electrode Capacitive Deionization (FCDI)

While flow-electrode CDI is a promising desalination technology that has major advantages when the electrodes are operated in the short-circuited closed-cycle (SCC) mode, little attention has been paid to the water recovery rate, which, in the SCC mode, is determined by the need for partial replacement of the saline electrolyte of the flow electrodes. Results of this study show that an extremely high water recovery rate of ∼95% can be achieved when desalting a 1000 mg NaCl L^-1 brackish influent to a potable level of 150 mg L^-1. The improved performance with regard to the electrical cost is related, at least in part, to the alleviated concentration polarization at the membrane/electrolyte interface during electrosorption. In effect, the current efficiency decreases with an increase in the water recovery rate. This finding is ascribed to inevitable co-ion leakage since the flow electrodes reject ions with the same charge. In addition, water transport across the ion exchange membranes also influences the water recovery rate. The effect of partial replacement of the saline electrolyte during (semi-)continuous operation requires particular consideration because the associated dilution of the carbon content in the flow electrodes results in a decrease in process performance.