Mechanistic investigations of antimony‐catalyzed polycondensation in the synthesis of poly(ethylene terephthalate)

Abstract The chemical aspects of poly(ethylene terephthalate) synthesis via the antimony‐catalyzed polycondensation of hydroxy ethylene terephthalate end groups were studied to elucidate its mechanism. A polycondensation mechanism was proposed in which activation occurs by the formation of a chelate ligand on antimony composed of the hydroxyl end group and alcoholic oxygen of the ester of the same end group. The rate‐determining step of the polycondensation reaction was concluded to be the coordination of a second chain end to antimony. The low activity of antimony at a high concentration of hydroxyl end groups was proposed to result from the competition between hydroxyl end groups and the chelate structure leading to the transition state. The high selectivity of antimony is probably due to its relatively low Lewis acidity. Moreover, antimony was found to stabilize hydroxyl end groups against degradation by preventing their complexation to carbonyl functionalities. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1049‐1059, 2006