Radiative Cooling and Protective Clothing Through Lamination of Hierarchically Porous Membrane

Abstract Personal protective clothing is designed to safeguard medical personnel from highly infectious diseases. However, it often compromises comfort, especially when worn outdoors during epidemics like the global COVID‐19 outbreak. This can lead to discomfort and even heatstroke. To tackle this issue, radiative cooling is incorporated into personal protective clothing by integrating hierarchically porous poly(vinylidene fluoride‐co‐hexafluoropropylene) (PVDF‐HFP) membranes into the fabric. These membranes possess a remarkable solar reflection rate of 96.9% and a strong mid‐infrared emittance of 95.2%. In practical scenarios, when exposed to clear sunny weather at midday, wearing radiative cooling personal protective clothing has the potential to reduce the temperature by 4.7 °C compared to commercially available personal protective clothing. Moreover, the lamination of porous PVDF‐HFP membranes enhances the protective capacity by increasing the synthetic blood penetration pressure from 7 to 20 kPa. The manufacturing process is straightforward, cost‐effective, and aligns with industry standards, making it suitable for large‐scale implementation in epidemic prevention and control. This technology offers comfortable protection while minimizing the risk of heatstroke.