Recent Progress in Design Principles of Covalent Organic Frameworks for Rechargeable Metal‐Ion Batteries

Covalent organic frameworks (COFs) are acknowledged as a new generation of crystalline organic materials and have garnered tremendous attention owing to their unique advantages of structural tunability, frameworks diversity, functional versatility, and diverse applications in drug delivery, adsorption/separation, catalysis, optoelectronics, and sensing, etc. Recently, COFs is proven to be promising candidates for electrochemical energy storage materials. Their chemical compositions and structures can be precisely tuned and functionalized at the molecular level, allowing a comprehensive understanding of COFs that helps to make full use of their features and addresses the inherent drawback based on the components and functions of the devices. In this review, the working mechanisms and the distinguishing advantages of COFs as electrodes for rechargeable Li-ion batteries are discussed in detail. Especially, principles and strategies for the rational design of COFs as advanced electrode materials in Li-ion batteries are systematically summarized. Finally, this review is structured to cover recent explorations and applications of COF electrode materials in other rechargeable metal-ion batteries.