单宁酸
胶粘剂
木聚糖
环氧树脂
材料科学
复合材料
共价键
硅醇
胺气处理
高分子化学
化学工程
化学
催化作用
有机化学
工程类
图层(电子)
纤维素
作者
Weihua Li,Zhi Li,Tongda Liu,Guanben Du,Kelu Ni,Hongxing Yang,Hang Su,Sichen Liu,Chunyan Yin,Xin Ran,Wei Gao,Long Yang
标识
DOI:10.1016/j.conbuildmat.2023.132556
摘要
Biomass adhesives have long been a subject of widespread concern and study due to their cost-effectiveness and minimal environmental impact. In this study, an activated wood surface with epoxy groups (AWI) was created by uniformly applying 3-glycidoxypropyltrimethoxysilane (KH560) onto poplar veneer. Then the aminated xylan-oxidized tannic acid adhesive (2AX-OTA) was prepared based on the Schiff base reaction between the quinone of oxidized tannic acid (OTA) and the amine group of aminated xylan (AX). Eventually, the high-performance bonding interface was co-built by 2AX-OTA and AWI. The dry bonding strength of 2AX-OTA-AWI plywood achieved 3.86 MPa, while the wet bonding strength was measured at 2.41 MPa and 2.15 MPa after immersion in hot (63 °C)/boiling water for 3 h. FT-IR, 13C NMR, and XPS chemical analyses demonstrated that a triple cross-linked network structure of the bonding interface was co-constructed by imine covalent chain bridges and epoxy-amine network. This triple cross-linked network structure plays a crucial role in enhancing water resistance. This study presents a novel approach to designing multi-cross-linked networks for the synthesizing of eco-friendly and high-performance bio-based adhesives.
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