检出限
荧光
化学
异喹啉
螯合作用
碳酰肼
水溶液中的金属离子
色酮
核化学
亚甲基
组合化学
亚甲蓝
线性范围
离子
光化学
无机化学
色谱法
立体化学
有机化学
催化作用
物理
量子力学
光催化
作者
Haiyan Xu,Shanzhu Zhang,Chengfang Zhang,Yu Wang,Xinkuan Chen
标识
DOI:10.1016/j.saa.2022.121697
摘要
In this work, a selective chemosensor, (E)-N'-((4-oxo-4H-chromen-3-yl)methylene)isoquinoline-1-carbohydrazide (ENO), was rationally developed for colorimetric and fluorogenic detection of Zn2+ ions. It was readily synthesized from 4-oxo-4H-chromene-3-carbaldehyde and isoquinoline-1-carbohydrazide via one-step Schiff reaction. ENO exhibited excellent fluorescent response performances toward Zn2+ over a wide pH range in EtOH/H2O media, including a distinguished color change from colorless to gold, a low limit of detection (LOD) value (34 nM), strong complexation ability (1.36 × 105 M-1) and rapid identification (2 min). The sensing mechanism of ENO toward Zn2+ was proposed on the basis of the chelation-enhanced fluorescence (CHEF) process, which was further supported by IR studies and the density functional theory (DFT) calculation. Moreover, ENO presented here demonstrated outstanding capability in monitoring trace level of Zn2+ ions in real water samples, living cells as well as the on-site assay kit.
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