降冰片二烯
铑
四氟硼酸盐
化学
有机化学
催化作用
离子液体
作者
Suman Chakrabarty,Veronika M. Shoba,James M. Takacs
标识
DOI:10.1002/047084289x.rn02159
摘要
[36620-11-8] C14H16RhBF4 (MW 373.99) InChI = 1S/2C7H8.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*1-4,6-7H,5H2;;/q;;-1;+1 InChIKey = HAYDJWBQWOEERB-UHFFFAOYSA-N (precatalyst for enantioselective transformations and cross-coupling reactions) Alternate names: bis(norbornadiene)(tetrafluoroborato)rhodium, Rh(nbd)2BF4. Physical Data: mp 136.9–139.9 °C. Solubility: soluble in CH2Cl2, insoluble in water. Form Supplied in: red crystalline solid; limited availability. Handling, Storage, and Precautions: keep container tightly closed in a dry and well-ventilated place. Air and moisture sensitive. Store under inert gas. Avoid exposure to moisture and strong oxidizing reagents. Wear protective gloves/ protective clothing/ eye protection/ face protection.
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