煅烧
材料科学
扫描电子显微镜
电化学
化学工程
透射电子显微镜
解吸
比表面积
复合材料
吸附
分析化学(期刊)
纳米技术
化学
电极
催化作用
有机化学
物理化学
工程类
作者
Siqi Cheng,Wenna Li,Shunhua Xiao,Shuai Zheng,Zhuo Chen,Lizhen Hu,Qing Zhu,Bin Huang,Qingquan Liu,Quanqi Chen
标识
DOI:10.1016/j.jallcom.2020.156707
摘要
The effects of calcination temperature on the physical and electrochemical performance of the Na4MnV(PO4)3/C composites, which are prepared by a sol-gel method combined with the subsequent calcination in inert atmosphere, are reported in this work. The Na4MnV(PO4)3/C composites are investigated by x-ray diffraction (XRD), N2 adsorption/desorption isothermal, scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy and electrochemical measurements. The specific surface area, disorder of carbon, diffusion coefficients of Na+ (DNa) and electrochemical performance of Na4MnV(PO4)3/C composites are greatly influenced by the calcination temperature. The surface area and disorder of carbon of Na4MnV(PO4)3/C substantially decrease with the calcination temperature increasing. While the DNa and electrochemical performance of Na4MnV(PO4)3/C composites improve with the calcination temperature from 650 to 750 °C and then degrade with the calcination temperatures from 750 to 850 °C. The results reveal that the optimal calcination temperature for the Na4MnV(PO4)3/C composites is 750 °C and the corresponding Na4MnV(PO4)3/C composite possesses the highest capacity and the best rate capability and cyclability amongst all these Na4MnV(PO4)3/C composites in this work.
科研通智能强力驱动
Strongly Powered by AbleSci AI