材料科学
潜热
气凝胶
复合数
化学工程
聚乙二醇
PEG比率
纤维素
复合材料
制作
热力学
医学
物理
工程类
病理
经济
替代医学
财务
作者
Heng Wang,Yong Deng,Fuzhong Wu,Huixin Jin,Yilin Liu,Jinlong Zheng
标识
DOI:10.1016/j.solmat.2021.111236
摘要
In this work, the latent heat enhanced polyethylene glycol (PEG)/cellulose aerogel (CA)-dopamine form-stable composite phase change materials (PCD fs-CPCMs) were constructed by facile in-situ fabrication method based on the freeze casting. Under the simultaneous synergistic effect of CA and dopamine modification, the PCD fs-CPCMs achieved ultra-high encapsulation capacity of ~95 wt% and latent heat of ~194.3 J/g. Furtherly, compared with before the dopamine modification, the latent heat of PCD fs-CPCMs was increased by ~18.9%, and the difference between theoretical and experimental value was significantly reduced, indicating that the modification effectively promoted phase change behavior and improved heat storage characteristic of PEG. The ultra-high encapsulation capacity was mainly attributed to the lightweight and porous characteristic of CA and the effective entanglement and combination of PEG molecular chain. The increased latent heat was mainly ascribed to the construction of new combination approaches among PEG, CA and dopamine, resulting in the weakening of hydrogen bond effect (before and after modification: O-H⋯O > O-H⋯N or N-H⋯O) so that the confinement effect of surfaces was weakened and modified surface-induced phase change behavior was promoted. Moreover, the PCD fs-CPCMs exhibited excellent chemical compatibility, reasonable heat storage and release rates, and acceptable thermal reliability and stability.
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