过硫酸盐
化学
催化作用
单线态氧
热解
罗丹明B
降级(电信)
亚甲蓝
电子顺磁共振
聚丙烯腈
甲基橙
水处理
化学工程
吸附
无机化学
光催化
有机化学
氧气
废物管理
工程类
核磁共振
聚合物
电信
物理
计算机科学
作者
Yi Hu,Dezhi Chen,Shoujun Wang,Rui Zhang,Yichuan Wang,Meng Li
标识
DOI:10.1016/j.seppur.2021.119791
摘要
Carbon materials are becoming the first choice for activating persulfate due to their environmental friendliness, high chemical stability, and metal-free leaching. However, the preparation of efficient carbon catalyst and the in-depth analysis for persulfate activation is still insufficient. Herein, N-doped porous carbons (NPCs) were prepared by the pyrolysis of polyacrylonitrile and used to trigger peroxymonosulfate (PMS) for degrading organic pollutants in water. The results showed that the optimized NPC-700, with large specific surface area, rich pore structure, high content of pyridinic N and graphitic N, as well as excellent oxygen-containing functional groups, possessed the best performance in activating PMS to degrade methylene blue (MB) with 99.15% degradation rate in 30 min. Furthermore, the NPC-700 delivered high stability under a wide pH from 3.51 to 11.15. The radical quenching experiments and electron paramagnetic resonance (EPR) spectroscopy revealed that •OH, O2•-, SO4•- and 1O2 active species were involved in the catalytic oxidation of MB. Besides, the NPC-700/PMS system exhibited excellent degradation performance for various organic dyes, including rhodamine B, acid orange 7, and methyl orange. This study not only provides a promising metal-free catalyst for the removal of organic pollutant in water, but also promotes the sustainable development of carbon-based materials.
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