化学
催化作用
偶联反应
有机合成
高分子化学
柠檬酸
金属
组合化学
有机化学
表征(材料科学)
纳米技术
材料科学
作者
Mostafa Koolivand,Mohsen Nikoorazm,Arash Ghorbani‐Choghamarani,Bahman Tahmasbi
摘要
Citric acid with three carboxylic groups was used as an outstanding chelating agent was utilized for the preparation of Cu–citric acid metal–organic framework (Cu–CA–MOF). The prepared MOF was characterized by FT‐IR, XRD, EDS, AAS, SEM, WDX and BET analysis. N 2 adsorption–desorption isotherms indicated acceptable BET surface area for Cu–CA–MOF. SEM images were shown that Cu–CA–MOF has geometric polyhedral shapes. Also, catalytic activity of Cu–CA–MOF successfully examined for the Suzuki–Miyaura cross‐coupling reaction and chemoselective oxidation of sulfides to sulfoxides.
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