淀粉
氢氧化钠
傅里叶变换红外光谱
扫描电子显微镜
化学
溶剂
核化学
吸水率
钠
吸收(声学)
红外光谱学
材料科学
有机化学
化学工程
工程类
复合材料
作者
Chi Khang Van,Phuong-Dong Nguyen,Thanh Tran,H C,Trung-Kien Tran,Tuan Q. Nguyen
出处
期刊:IOP conference series
[IOP Publishing]
日期:2021-03-01
卷期号:1092 (1): 012081-012081
被引量:3
标识
DOI:10.1088/1757-899x/1092/1/012081
摘要
Abstract Carboxymethyl jackfruit seed starch (CMS) was synthesized under different reaction conditions. The influence of sodium hydroxide concentration, monochloroacetic acid (MCA) concentration, IPA-water ratio, solvent-starch ratio, reaction time, and temperature were evaluated for degree of substitution (DS). Results have shown that the optimal DS of 0.68 was obtained at 50 °C, 90 minutes in solvent-starch ratio and isopropanol-water were 8:1 and 10:0. The ratio of sodium hydroxide and monochloroacetate acid moles to anhydroglucose unit (AGU) moles for the optimal DS were 1 and 1. Scanning electron microscope (SEM) of CMS particles showed the starch grain structure remains the same but the surface appeared many alveolar holes and no longer smooth as MS. Fourier transform infrared spectra (FTIR) of CMS and MS confirmed that carboxymethylation takes place on native starch molecules when the absorption band appears at a wavenumber of 1643 cm −1 corresponding to the vibrations of featured functional C=O group in CMS structure.
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